Raw Materials & Fuel Requirement For Pidgeon Process Magnesium Production

Date:2021-01-03 Source:zk corp Views:

1. Dolomite

See Diagram 1 for the chemical composition of Eczacibasi Esan’s dolomite sample (Based on the Report of Dolomite Composition Analysis and Processing Test of Eczacibasi Esan)

 

Diagram 1: Chemical composition of dolomite sample

MgO

CaO

SiO2

TiO2

Al2O3

Fe2O3

Na2O

K2O

Zn

SO3

MnO

P2O5

L.O.I

21.11

30.78

0.24

0.016

0.02

0.016

0.024

0.006

0.0004

0.036

0.0042

0.010

46.71

     

The size of dolomite shall be within 10~50mm before input into the pre-heater.

 

2. Ferrosilicon

The size of Ferrosilicon shall not be more than 100mm when transported into factory. And the chemical composition shall comply with Diagram 2.

 

Diagram 2: Chemcial composition of Ferrosilicon

Si

Al

P

S

Mn

≥75

≤1.5

≤0.035

≤0.02

≤0.4

 

 

3. Fluorite

Fluorite bought from outside shall be packed in bags when transported into the factory. The size of -200 mesh shall be more than 95% (-0.074mm>95%); The chemical composition of fluorite shall comply with Diagram 3.

 

Diagram 3: Chemical composition of fluorite.

Composition

CaF2

CaCo3

SiO2

H2O

%

≥95

≤3

≤1

<1

 

4. Fuel

Both rotary kiln and reduction furnace are fired by natural gas, while refining process by electricity.

 

Calorific value of natural gas: ≈8250kcal/Nm3. See Diagram 4 for chemical composition.

 

Diagram 4: Chemical composition of natural gas

CH4

C2H6

C3H8

C4H10

CO2

O2

N2

H2S

Other Carbons

min

max

mxs

msx

max

max

msx

max

max

82%

12%

4%

2.5%

3%

0.5%

5.8%

5.35mg/m3

1%

 

 

5. Solvent

Mg crystal after reduction shall be refined in chloride solvent. High quality Mg can be obtained after removing the metal and non-metal impuritiesl.

 

See Diagram 5 for list of solvent used in crude Mg refining.

 

Diagram 5: List of solvent used in crude Mg refining

Type of solvent

Basic solvent

(2# Calcium solvent)

Refining solvent

Power solvent (Covering solvent)

New solvent

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